張宗仁教授

e-mail: asdew@mail.nsysu.edu.tw

 cc_chang.jpg (16409 bytes)
理學院院長(1989-1995)
化學研究所所長 (1987-1989)
教授 (1985)
高雄師範大學化學系教授兼系主任 (1982-1985)
副研究員，中山科學院 (1977)
美國科羅拉多大學博士 (1977)
清華大學化學所碩士 (1970)
淡江大學化學系學士(1967)
研究興趣
1.無機合成
2.主族金屬有機化合物
代表著作
1. Chang, C. C.; Lin, S. C.; Tsay, J. O.; Lin, L. K. "Synthesis on Al-Mg Polynuclear Bridged Complexes (II)" J. Chin.Chem. Soc.,1992, 39, 55.
2. Her, T. Y.; Chang, C. C.; Liu, L. K. "Synthesis and Molecular Structures of an Unusual Cyclictertrameric Orgametallic Complexes,{(CH3)2Al[m-N(i-C3H7)2]2Mg(CH3)}4 , Containing Tri-coordinate Magnesiums and a Linear Dimer , {(CH3)2Al[m-N(C2H5)2]2 Mg(CH3)}2, Containing Tetra-coordinate Magnesiums" Inorg. Chem. 1992, 31, 2291.
3. Her, T. Z.; Chang, C. C.; Tsai, J. O.; Liu, L. K.; Chang, H. C. "Synthesis, Spectroscopic Studies, and Crystal Structures of X4Al2(NR2)2[X=Br, C2H5, CH3; R=C2H5, i-C3H4] " . Polyhedron 1993, 12, 731.
4. Her, T. Y.; Chang, C. C.; Lee, G. H.; Peng, S. M. "A Tricoordinate-Maganesium Silylamide Complex: {[(CH3)3Si]2N}2MgO(CH2CH2)2OMg {N[Si(CH3)3]2}2, " J. Chin, Chem.Soc. 1993, 40, 315.
5. Chang, C. C.; Huang, C. C.; Tsai, J. O.; Lee, M. D.; Cheng, C. L.; Lee, A. W. "Synthesis and Molecular Structures of Polynuclear Aluminum Complexes Rn+2AlnL2(n=3,4; L=diamine,triamine) Containing Penta-coordinate Al Atoms" Polyhedron, 1993, 12, 2125.
6. Chang, C. C.; Lee, W. H.; Her, T. Y.; Lee, G. H.; Peng, S. M.; Wang, Y. "Chemical Reaction of
{(CH3)2Al[m-N(i-C3H7)2]2Mg(CH3)}4 and {(CH3)2Al[m-N(i- C2H5)2]2Mg(CH3)}2 .Crystal Structures of {(CH3)2Al[m-N(i-C3H7)2]2Mg I}2 , [(CH3)2Al[m- O-t-C4H9)2Mg(O-t-C4H9)] 2 , (CH3)2Al[m-N(i-C3H7)2 m-OC2H5)2Mg, and [ (CH3)2Al]2( m- O-t-C4H9)4Mg" J. Chem. Soc., Dalton Trans. 1993
7. Her, T. Y.; Chang, C. C.; Lee, G. H.; Peng, S. M.; Wang, Y. "Syntheses and Crystal Structures of Polynulear Organoaluminum-magnesium Complexes and Its Oxidative Reaction Products" Inorg. Chem. 1994, 33, 99.
8. Li, M. D.; Chang, C. C.; Lin, S. T.; Lee, G. H.; Wang, Y.; Peng, S. M. "Synthesis and Crystal Structure of the Novel Organoaluminum Complexes : {Al(CH3C(CH2NH)3(Al(CH3 )2)3}" Organomet Chem. 1994 , 13, 1504
9. B. Srinivas, C. C. Chang, C. H. Chen, I. T. Chen, M. Y. Chiang, Y. Wang, G. H. Lee, Synthesis, Characterixzation and Crystal Structures of Isothiocyanate and Carbodiimide Complexes Derived from Organomagnium Reagents: Insertion of Isothiocyanates and Carbodiimides into Mg-X (X=C, N) Bonds, J. Chem. Soc. Dalton Trans. 957 (1997).
10. M. D. Li, C. C. Chang, M. Y. Chiang, S. M. Peng, Y. Wang, G. H. Lee, Substitution Reactions of Organoaluminum Amide Complexes [Al(m-NR2)nCl3-n]2 (R=Et,iPr; n≦3) with LiNR'R" (R'=R"=iPr, Et; R'=H, R"=iPr): Crystal Structure of [Al(m-NEt2)(NiPr2)X]2 (X=Cl, H) and AlCl3(NiPrH2)2{[Al(NH3)(NH2)[Al (NiPrH)(NiPR) Cl]2}2. Inorg. Chem. 36, 1955 (1997).
11. C. C. Chang, J. H. Chen, B. Srinivas, M. Y. Chiang, G. H. Lee, Y. Wang, Insertion Reactions of Isocyanates, Isothiocyanates and Carbondisulfide into Mg-C Bonds of Polynuclear Aluminum-Magnesium Compounds: Synthesis, Characterization, and Crystal Structures, Organometallics (accepted).